®®®® SIIA Público

Título del libro: Pincer Compounds: Chemistry And Applications
Título del capítulo: Benzene-derived organometallic pincer compounds bearing six-membered metallacycles and up

Autores UNAM:
LUCERO GONZALEZ SEBASTIAN; DAVID MORALES MORALES;
Autores externos:

Idioma:
Inglés
Año de publicación:
2018
Palabras clave:

5,6-membered metallacycles; 6,6-membered metallacycles; 7,6-membered metallacycles; Atropisomerism; Catalysis; Cross coupling reactions; Flexible pincer systems; Hemilabile pincer systems; Hybrid pincer compounds; Metallacycles; Noninnocent ligands; Nonsymmetric pincer complexes; Palladacycles; Pincer systems; Suzuki-Miyaura couplings; Unstrained pincers


Resumen:

This chapter describes the chemistry of pincer compounds including metallacycles larger than 5, i.e., 6 and 7 membered, the synthetic procedures for the attaining of the ligands, and metalation procedures to produce the corresponding complexes. The consequences of increasing the size of the metallacycles are also discussed both in terms of structure of the complexes and their effects in catalysis when the complexes were designed or employed for these purposes in different transformations. © 2018 Elsevier Inc. All rights reserved.


Entidades citadas de la UNAM: