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Título del libro: Raft Polymerization: Methods, Synthesis And Applications: Volume 1 And 2
Título del capítulo: RAFT Crosslinking Polymerization

Autores UNAM:
PATRICIA PEREZ SALINAS; PORFIRIO LOPEZ DOMINGUEZ; ALBERTO ROSAS ABURTO; EDUARDO VIVALDO LIMA;
Autores externos:

Idioma:

Año de publicación:
2021
Resumen:

A review on polymer synthesis, applications, and mathematical modelling of polymer network formation by radical copolymerization of multi-olefinic monomers, in the presence of reversible addition-fragmentation chain transfer (RAFT) controllers, is presented. Our review builds on and updates content presented in an existing previous review on the topic [25], but it includes topics not considered before such as synthesis of reversible polymer networks based on ionic bonds, as well as the syntheses of materials described as nanogels, microgels, core-crosslinked stars, thermo- or pH- responsive materials, self-healing polymer networks, ?arm-first? stars, or hyperbranched polymers that can be formed by RAFT (co)polymerization of similar components under different reaction conditions before gelation. Another distinctive characteristic of our chapter is that it includes a survey on the modelling of polymer network formation by RAFT (co)polymerization of vinyl/divinyl monomers, where significant progress has been achieved. © 2022 WILEY-VCH GmbH, Boschstr. 12, 69469 Weinheim, Germany.


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