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Título del libro:
Título del capítulo: Monoclinic Phase Stabilization with the High-Entropy Ceramics Approach in the Pseudobinary System In3Ti2AO10?In6Ti6BO22 (A: Al, Ga; B: Mg, Zn)

Autores UNAM:
VICTOR EMMANUEL ALVAREZ MONTAÑO; SUBHASH SHARMA; ALEJANDRO CESAR DURAN HERNANDEZ;
Autores externos:

Idioma:

Año de publicación:
2025
Palabras clave:

Aluminum oxide; Ceramic capacitors; Gallium compounds; Lithium compounds; Magnesium alloys; Sintering; Titanium dioxide; Zinc alloys; Zinc sulfide; Coordination number; Dielectrics property; Divalent cation; High-entropy ceramic; Monoclinic phase; Phase stabilization; Pseudo-binary systems; Solid state reaction method; Trivalent cations; XRD; Sintered alumina


Resumen:

In the pseudobinary system In3Ti2AO10?In6Ti6BO22 (A: trivalent cation; B: divalent cation) both A and B have coordination number CN = 5 (trigonobipyramidal sites). In this work, this system was studied by means of the high-entropy ceramicsHigh entropy ceramics approach. The compound In12Ti10AlGaMg0.5Zn0.5O42 was obtained by the solid-state reaction method, and its phase stability in the 1300?1400 °C range of temperatures was evaluated. XRD and SEM facilities were used to characterize the present phases. EDS with elemental mapping analysis was used to demonstrate the configurational high-entropy dimension. Samples of 120 mg were pelletized and sintered in high alumina crucibles, and silver painted as capacitors-like to make dielectricDielectric measurements from room temperature to 550 °C in the frequency range of 10?1000 kHz, and their results are compared with closely related compounds. © The Minerals, Metals & Materials Society 2025.


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